I'm not getting anything out of their respective characterizations that would be fun to play off each other. They're different, obviously, but nothing mirror/flipped different to the point of interest.
Sure, she is magic and he is tech. But Hal himself isn't tech-oriented, he has no idea how any of the tools (fighter jets or power rings) operate, he is just a modern-day cowboy. Is there anything notable about pairing off a cowboy and a greek goddess? Not really, no, its different but nothing iconically-different.
Hal-Barry and Hal-Bruce are more interesting matches, honestly.