>>105312179I considered that, but just "Oh I recognize that person from Peter's rogues gallery" wouldn't explain why she immediately zeroes in on HER and calls LIV by her first name, when there's like 3 or 4 other bad guys in the room. She doesn't respond to Kingpin, Prowler, Scorpion or Hammerhead - but as soon as she sees Doc Ock, we see that they clearly personally knew one another.
Also, are we sure Liv ever even met blonde!Peter, let alone fought him? She seems to be in good standing with society, cushy private sector job and her vids get used in preppy science classes - I guess you could chalk that up to Kingpin's influence too, but when she sees Spidey, her reaction isn't "So, the boss didn't finish you off after all! More fun for me, wallcrawler!" She's clearly banking on the fact that Spidey DOESN'T know who she is even before she recognizes that he's an AU Spidey, so I took it as a version of Doc Ock who's only just begun her criminal career.