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What is an excitation of a quantum field in mathematical terms?

If I would take the analogy of a quantum field being an infinite collection of coupled harmonic oscillators I could see the excitation as the presence of a quanta at a position in space, or per extension I could understand it through the occupation number representation. Both feel like wrapping a concept that can be defined more rigorously, however.

If I define the quantum field as an operator-valued distribution on a spacetime manifold , could an excitation at be defined by being trivial? If yes, what would constitute being trivial in this case?