[Chemistry] Electron Configuration - Electron Sequence?

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How would one figure out the number of electrons per orbital using the electron configuration?

For instance, 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d6, or [Ar] 3d6 4s2 for short, is the electron configuration for iron. The electron arrangement for iron from the nucleus outwards is 2, 8, 14, 2. I don't understand how to go from the configuration to the arrangement. May anyone elaborate?