>>14278176When I was a teenager I used to wipe my face with paper towels with vodka in them.
Based on my experience I think that it would sting your eyes, your skin would get very dehydrated very fast if you did it regularly, the fumes might be surprisingly overwhelming: the evaporation from the surface of a vodka ice for a few moments before you take a sip is much less intense than the evaporation of a layer of vodka at skin temperature all around your mouth and nose until it has evaporated, if you had any acne then after a couple of dips you would no longer have any acne.
If you really wanted to do this I would recommend not using pure alcohol, and also rinsing straight away with water, at least to avoid the bulk of the fumes if nothing else.