Limitations of the Coulomb model
The Coulomb approximation follows from the assumptions that: surfaces are in atomically close contact only over a small fraction of their overall area; that this contact area is proportional to the normal force (until saturation, which takes place when all area is in atomic contact); and that the frictional force is proportional to the applied normal force, independently of the contact area. The Coulomb approximation is fundamentally an empirical construct. It is a rule-of-thumb describing the approximate outcome of an extremely complicated physical interaction. The strength of the approximation is its simplicity and versatility. Though the relationship between normal force and frictional force is not exactly linear (and so the frictional force is not entirely independent of the contact area of the surfaces), the Coulomb approximation is an adequate representation of friction for the analysis of many physical systems.
When the surfaces are conjoined, Coulomb friction becomes a very poor approximation (for example, adhesive tape resists sliding even when there is no normal force, or a negative normal force). In this case, the frictional force may depend strongly on the area of contact. Some drag racing tires are adhesive for this reason. However, despite the complexity of the fundamental physics behind friction, the relationships are accurate enough to be useful in many applications.