You are now Secretary of State Thaddeus "Thunderbolt" Ross, and are tasked with putting together a team of superpowered criminals to be sent on high-risk missions under the command of global governments.
A suicide squad, if you will. When not out on mission, your team will be imprisoned on the Raft: http://marvel.wikia.com/wiki/Raft

Pull anyone from Marvel comics or the MCU. Just make it interesting.